Rebuttal to: Polemic against conclusions drawn in “Palladium/iodide catalyzed oxidative carbonylation of aniline to diphenylurea: Effect of ppm amounts of iron salts” (J. Catal. 369 (2019) 257–266)
Articolo
Data di Pubblicazione:
2019
Citazione:
Rebuttal to: Polemic against conclusions drawn in “Palladium/iodide catalyzed oxidative carbonylation of aniline to diphenylurea: Effect of ppm amounts of iron salts” (J. Catal. 369 (2019) 257–266) / F. Ragaini, F. Ferretti, C. Gatti, D.R. Ramadan. - In: JOURNAL OF CATALYSIS. - ISSN 0021-9517. - 380(2019 Dec), pp. 391-395. [10.1016/j.jcat.2019.03.030]
Abstract:
In a recent paper on this Journal (J. Catal. 369 (2019) 257-266), we reported on the effect of ppm amounts of iron compounds on the palladium/iodide (and even palladium/chloride) catalytic system for the oxidative carbonylation of aniline to diphenylurea. In a "Polemic" against our work, Gabriele and coworkers argued against some of the conclusions we had drawn and even against our experimental practice. Here, we reply in detail to this polemic. Some of the content of the latter is due to some misunderstanding, whereas some assertions are untenable and in contrast with experimental data.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Aromatic amine; Carbon monoxide; Dimethoxyethane; Diphenylurea; Iodide; Iron chloride; Oxidative carbonylation; Palladium
Elenco autori:
F. Ragaini, F. Ferretti, C. Gatti, D.R. Ramadan
Link alla scheda completa:
Link al Full Text: