Data di Pubblicazione:
2005
Citazione:
Catalytic amination reactions mediated by Co(II) Schiff base complexes / A. Caselli, E. Gallo, F. Ragaini, A. Oppezzo, S. Cenini. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 690:8(2005), pp. 2142-2148. ((Intervento presentato al 3. convegno Euchem Conference on Nitrogen Ligands in Organometallic Chemistry and Homogeneous Catalysis tenutosi a Camerino nel 2004 [10.1016/j.jorganchem.2005.01.021].
Abstract:
Co(acacen), 1, (acacen = 2,11-dihydroxy-4,9-dimethyl-5,8-diaza-2,4,8,10-dodecatetraene dianion) was found to be a highly efficient catalyst for the allylic amination of non activated alkenes, using N-(p-toluensulfonyl)iminophenyliodinane (PhI=NTs) as nitrene precursor. This reactivity has been extended to the less reactive C-H bond of toluene. The effect of reaction times and of added cosolvent on yields and selectivities was investigated. Under the best conditions, allylic amines were obtained in a 40-70% isolated yield. A complex derived from the stoichiometric reaction of Co(acacen), 1, with PhI=NTs has been isolated and spectroscopically characterized. Such a complex, although not able to transfer its NTs moiety to alkenes, is still active in catalyzing allylic amination of cyclohexene.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
cobalt; schiff bases; N-(p-toluensulfonyl)iminophenyliodinane; amination reactions; allylic amines
Elenco autori:
A. Caselli, E. Gallo, F. Ragaini, A. Oppezzo, S. Cenini
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