Using Ring Strain to Inhibit a Decomposition Path: First Synthesis of an Alkyl-BIAN ligand (Alkyl-BIAN = bis(alkyl)acenaphthenequinonediimine)
Articolo
Data di Pubblicazione:
2005
Citazione:
Using Ring Strain to Inhibit a Decomposition Path: First Synthesis of an Alkyl-BIAN ligand (Alkyl-BIAN = bis(alkyl)acenaphthenequinonediimine) / F. Ragaini, M. Gasperini, E. Gallo, P. Macchi. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - :8(2005), pp. 1031-1033.
Abstract:
N-Alkyl imines of acenaphthenequinone are not stable because an isomerization occurs that releases part of the ring strain of the initially formed imine by changing the hybridization of one of the ring carbon atoms from sp2 to sp3. However, if an even more stained ring is present in the alkyl group, the isomerization becomes unfavorable and the compound is stable.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Acenaphthene derivates; coordination strength; bis(aryl)acenaphthenequinonediiimine; complexes; amines
Elenco autori:
F. Ragaini, M. Gasperini, E. Gallo, P. Macchi
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