The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar=3,5-(CF3)(2)C6H3)
Articolo
Data di Pubblicazione:
2009
Citazione:
The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar=3,5-(CF3)(2)C6H3) / S.M. Fantauzzi, E. Gallo, A. Caselli, F.A.C. Ragaini, N. Casati, P. Macchi, S. Cenini. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 2009:26(2009), pp. 3952-3954.
Abstract:
The complex Ru(TPP)(NAr)(2) inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Transition-metal-complexes; hydrogen-atom transfer; ruthenium porphyrins; manganese-porphyrins; aryl azides; intramolecular amidation; aziridination; hydrocarbons; functionalization; activation
Elenco autori:
S.M. Fantauzzi, E. Gallo, A. Caselli, F.A.C. Ragaini, N. Casati, P. Macchi, S. Cenini
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