Complete 1H and 13C NMR spectral assignment of of α- and β-adenosine, 2'-deoxyadenosine and their acetate derivatives
Articolo
Data di Pubblicazione:
2007
Citazione:
Complete 1H and 13C NMR spectral assignment of of α- and β-adenosine, 2'-deoxyadenosine and their acetate derivatives / P. Ciuffreda, S. Casati, A. Manzocchi. - In: MAGNETIC RESONANCE IN CHEMISTRY. - ISSN 0749-1581. - 45:9(2007 Sep), pp. 781-784. [10.1002/mrc.2036]
Abstract:
1H and 13C NMR chemical shifts of α- and β-anomers of adenosine, 2'-deoxyadenosine and their acetate derivatives were completely and definitely assigned using the concerted application of one- and two-dimensional experiments (gCOSY, gNOESY, gHSQC, and gHMBC). The influence of the stereochemistry of the purine base on the NMR data of the hydrogen and carbon atoms of the furanose moiety was investigated.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
β and α-adenine nucleosides; β- and α-adenine nucleoside acetates; 13C NMR; 1H NMR; gCOSY; gHMBC; gHSQC; gNOESY
Elenco autori:
P. Ciuffreda, S. Casati, A. Manzocchi
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