Bacterial monooxygenase mediated preparation of nonracemic chiral oxiranes: study of the effects of substituent nature and position
Articolo
Data di Pubblicazione:
2004
Citazione:
Bacterial monooxygenase mediated preparation of nonracemic chiral oxiranes: study of the effects of substituent nature and position / S. Bernasconi, F. Orsini, G. Sello, P. Di Gennaro. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - 15:10(2004 May 24), pp. 1603-1606. [10.1016/j.tetasy.2004.04.005]
Abstract:
Monooxygenation of styrene derivs. using a recombinant E. coli biocatalyst represents an efficient way to prep. the corresponding oxiranes. The present work examines the electronic and geometric effects of the ring substituents and reveals an enzymic activity characterized by relaxed specificity and high stereoselectivity.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
recombinant escherichia-coli; pseudomonas-fluorescens st; nonaqueous-phase liquids; styrene monooxygenase; enantiopure epoxides; diodegradation; bioreactors; phenanthrene; degradation; system
Elenco autori:
S. Bernasconi, F. Orsini, G. Sello, P. Di Gennaro
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