Large, Concentration-dependent Enhancement of the Quadratic Hyperpolarizability of [Zn(CH3CO2)2(L)2] in CHCl3 on Substitution of Acetate by Triflate
Articolo
Data di Pubblicazione:
2003
Citazione:
Large, Concentration-dependent Enhancement of the Quadratic Hyperpolarizability of [Zn(CH3CO2)2(L)2] in CHCl3 on Substitution of Acetate by Triflate / F. Tessore, D. Roberto, R. Ugo, P. Mussini, S. Quici, I.Ledoux Rak, J. Zyss. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 42:4(2003), pp. 456-459. [10.1002/anie.200390138]
Abstract:
An unexpected dependence on concentration was found for the quadratic hyperpolarizability β of Zn complexes with stilbazole and CF3SO3-ligands (see values given), which reaches very large values on dilution. This is surprising, because the concentration used for determining β is traditionally not given in the literature, probably because it is a molecular property that should not vary with concentration. The origin of this effect is also reported.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
F. Tessore, D. Roberto, R. Ugo, P. Mussini, S. Quici, I. Ledoux Rak, J. Zyss
Link alla scheda completa: