STEREOSELECTIVE SYNTHESIS OF (E)-2-ALKENE-1,4-DIOLS VIA METALATED ALLYLIC SULFOXIDES

Articolo
Data di Pubblicazione:
1986
Citazione:
STEREOSELECTIVE SYNTHESIS OF (E)-2-ALKENE-1,4-DIOLS VIA METALATED ALLYLIC SULFOXIDES / R. ANNUNZIATA, M. CINQUINI, F. COZZI, L. RAIMONDI, S. STEFANELLI. - In: TETRAHEDRON. - ISSN 0040-4020. - 42:19(1986), pp. 5443-5450. [10.1016/S0040-4020(01)82095-0]
Abstract:
Reaction of allyl sulphinyl anion with chiral α-methylaldehydes affords α- or γ-adducts in highly regio-controlled fashion, depending on reaction conditions. From the α-adducts syn (E)-2-alkene-1,4-diols are obtained as major (d.r. 2:1 ~ 28:1) products by thiophile promoted desulphurization.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
R. Annunziata, M. Cinquini, F. Cozzi, L. Raimondi, S. Stefanelli
Autori di Ateneo:
RAIMONDI LAURA MARIA ( autore )
Link alla scheda completa:
https://air.unimi.it/handle/2434/184197

Aree Di Ricerca

Settori


Settore CHIM/06 - Chimica Organica