A computational study of the 1,4-addition of lithium enolates to conjugated carbonyl-compounds
Articolo
Data di Pubblicazione:
1991
Citazione:
A computational study of the 1,4-addition of lithium enolates to conjugated carbonyl-compounds / A. Bernardi, A. Capelli, A. Comotti, C.M.A. Gennari, C. Scolastico. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 32:6(1991), pp. 823-826. [10.1016/S0040-4039(00)74897-0]
Abstract:
Transition structures A-D were located on the MNDO surface for the reaction of the lithium enolate of acetaldehyde with acrolein. Their relative 3-21G/MNDO energies were computed. They allow a qualitative rationalization of the observed stereoselectivity trends in the title reaction.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
complexes
Elenco autori:
A. Bernardi, A. Capelli, A. Comotti, C.M.A. Gennari, C. Scolastico
Link alla scheda completa: