BINOL derived C2-symmetric bis-sulfinates as efficient sulfinyl transfer agents in the synthesis of tert-butyl sulfoxides

Articolo
Data di Pubblicazione:
2012
Citazione:
BINOL derived C2-symmetric bis-sulfinates as efficient sulfinyl transfer agents in the synthesis of tert-butyl sulfoxides / N. Gaggero, D.C.M. Albanese. - In: TETRAHEDRON. - ISSN 0040-4020. - 68:35(2012), pp. 7129-7132.
Abstract:
The reaction of novel C2-symmetric bis-sulfinate esters derived from (R)-BINOL with Grignard reagents affords tert-butyl sulfoxides in ee up to 97%. The desired enantiomer can be generated at will by the proper selection of BINOL.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
N. Gaggero, D.C.M. Albanese
Autori di Ateneo:
ALBANESE DOMENICO CARLO MARIA ( autore )
Link alla scheda completa:
https://air.unimi.it/handle/2434/175448

Aree Di Ricerca

Settori


Settore CHIM/06 - Chimica Organica