Unexpected coordination behavior of ruthenium to a polymeric α-diimine containing the poly[bis(arylimino)acenaphthene] fragment
Articolo
Data di Pubblicazione:
2021
Citazione:
Unexpected coordination behavior of ruthenium to a polymeric α-diimine containing the poly[bis(arylimino)acenaphthene] fragment / F. Ferretti, L. Rota, F. Ragaini. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 518:(2021 Apr 01). [10.1016/j.ica.2021.120257]
Abstract:
Use of homogeneous catalysts poses the problem of their recovery at the end of the reaction. A possible strategy to circumvent this problem is to make the ligand part of a polymer with limited solubility. In this work, we investigated the immobilization of complexes of Ar-BIAN ligands (Ar-BIAN = bis(arylimido)acenaphthene). We employed 4,4′-methylene-bis(aniline) as an amine able to bridge two acenaphthene moieties. However, the obtained product was a mixture of short-chain oligomers. A ruthenium complex of this mixture (Oligo-BIAN) was indeed catalytically active in the model hydrogenation of nitrobenzene to aniline by CO/H2O but the complexes were too soluble in the reaction mixture to allow for an easy recovery. We thus further extended the molecular weight of Oligo-BIAN by polymerizing it with terephthaloyl chloride obtaining a polyamide (Poly-BIAN). The latter was insoluble in all solvents but its ruthenium complex was catalytically inactive in the model reaction. An deeper investigation, showed that coordination mode of monomeric Ar-BIAN ligands and Oligo-BIAN to [Ru(CO)3Cl2(THF)] is differs from that of Poly-BIAN. This result was completely unexpected and constitutes a general warning not to give for granted the coordination mode of a complex to a functionalized polymer.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Heterogenized catalysts; N-ligands; Polymeric ligands; Ruthenium; Schiff bases
Elenco autori:
F. Ferretti, L. Rota, F. Ragaini
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