Asymmetric time-cross-correlation of nonequilibrium concentration fluctuations in a ternary liquid mixture
Articolo
Data di Pubblicazione:
2019
Citazione:
Asymmetric time-cross-correlation of nonequilibrium concentration fluctuations in a ternary liquid mixture / D. Brogioli, F. Croccolo, A. Vailati. - In: PHYSICAL REVIEW. E. - ISSN 2470-0045. - 99:5(2019), pp. 053115.1-053115.10. [10.1103/PhysRevE.99.053115]
Abstract:
Equilibrium phenomena are characterized by time symmetry. Thermodynamic fluctuations are also time-symmetric at equilibrium. Conversely, diffusion of a solute in a liquid in the presence of a gradient is a nonequilibrium phenomenon, which gives rise to long-range fluctuations with amplitude much larger than the equilibrium one for small enough wave number. In the case of diffusion in binary mixtures such fluctuations are time-symmetric, notwithstanding the fact that they are generated by a nonequilibrium condition. In this paper, we investigate diffusion of two solutes in a ternary liquid mixture by means of fluctuating hydrodynamics theory. We show that the time-cross-correlation function of the concentrations is not time-symmetric, hence showing that time symmetry is violated for such nonequilibrium fluctuations. We discuss the feasibility of experiments aimed at the detection of the asymmetry of the cross-correlation function of nonequilibrium concentration fluctuations in ternary mixtures, as envisaged in the Giant Fluctuations (NEUF-DIX) microgravity project of the European Space Agency.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
D. Brogioli, F. Croccolo, A. Vailati
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