Ruthenium(II) complexes bearing (NNN) ligand : catalytic evaluation of different solvent-mediated coordination modes
Articolo
Data di Pubblicazione:
2018
Citazione:
Ruthenium(II) complexes bearing (NNN) ligand : catalytic evaluation of different solvent-mediated coordination modes / S. Pellegrino, G. Facchetti, R. Gandolfi, M. Fuse`, E. Erba, I. Rimoldi. - In: CANADIAN JOURNAL OF CHEMISTRY. - ISSN 0008-4042. - 96:1(2018), pp. 40-43. [10.1139/cjc-2017-0487]
Abstract:
A new (NNN) tridentate ligand was prepared, and its ability to coordinate ruthenium(II) was evaluated. The presence of different functional groups on the ligand allows bi- or tri-coordinated complexes to be obtained depending on complexation conditions. The catalytic activity of both bidentate and tridentate complexes was studied in asymmetric transfer hydrogenation of different aryl ketones, showing a comparable behavior of the two complexes in terms of efficiency and stereoselectivity.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
tridentate ligand; asymmetric hydrogen transfer; asymmetric ketones reduction
Elenco autori:
S. Pellegrino, G. Facchetti, R. Gandolfi, M. Fuse`, E. Erba, I.S. Rimoldi
Link alla scheda completa:
Link al Full Text: