The Two-Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of[Mn(3-MeOsalen)(H2O)]ClO4 and K3[Fe(CN)6]
Articolo
Data di Pubblicazione:
1995
Citazione:
The Two-Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of[Mn(3-MeOsalen)(H2O)]ClO4 and K3[Fe(CN)6] / H. Miyasaka, N. Matsumoto, H. Ōkawa, N. Re, E. Gallo, C. Floriani. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION IN ENGLISH. - ISSN 0570-0833. - 34:13-14(1995), pp. 1446-1448. [10.1002/anie.199514461]
Abstract:
Cyclic tetrameric units (··Mn‐NC‐Fe‐CN··)4 (depicted on the right) construct the two‐dimensional network of the title compound. The layers thus formed are linked together by van der Waals contacts. The compound displays metamagnetism: ferromagnetic coupling is observed within layers and antiferromagnetic coupling between layers.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Magnetic properties; manganese compounds; Prussian blue; salen complexes
Elenco autori:
H. Miyasaka, N. Matsumoto, H. Ōkawa, N. Re, E. Gallo, C. Floriani
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