Building up an electrocatalytic activity scale of cathode materials for organic halide reductions
Articolo
Data di Pubblicazione:
2005
Citazione:
Building up an electrocatalytic activity scale of cathode materials for organic halide reductions / C. Bellomunno, D. Bonanomi, L. Falciola, M. Longhi, P.R. Mussini, L.M. Doubova, G. Di Silvestro. - In: ELECTROCHIMICA ACTA. - ISSN 0013-4686. - 50:11(2005), pp. 2331-2341. [10.1016/j.electacta.2004.10.047]
Abstract:
A wide study on the electrochem. activity of 4 model org. bromides was carried out in MeCN on 9 cathodes of widely different affinity for halide anions (Pt, Zn, Hg, Sn, Bi, Pb, Au, Cu, Ag), and the electrocatalytic activities of the latter were evaluated with respect to 3 possible inert ref. cathode materials, i.e. glassy C, B-doped diamond, and fluorinated B-doped diamond. A general electrocatalytic activity scale for the process is proposed, with a discussion on its modulation by the configuration of the reacting mol., and its connection with thermodn. parameters accounting for halide adsorption.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Organic electrocatalysis; Organic halide reduction; Halide adsorption; Specifically interacting cathode materials; Non-interacting cathode materials
(GC, BDD, FBDD)
Elenco autori:
C. Bellomunno, D. Bonanomi, L. Falciola, M. Longhi, P.R. Mussini, L.M. Doubova, G. Di Silvestro
Link alla scheda completa: