Stereoselective aldol reactions of [gamma]-thiobutyrolactone : The benzaldehyde anomaly

Articolo
Data di Pubblicazione:
1990
Citazione:
Stereoselective aldol reactions of [gamma]-thiobutyrolactone : The benzaldehyde anomaly / C. Gennari, A. Oliva, F. Molinari, U. Piarulli. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 31:17(1990), pp. 2453-2456.
Abstract:
Different protocols (lithium enolate reactions, fluoride catalyzed and Lewis acid mediated silyl ketene acetal reactions) were studied to achieve stereoselectivity in the aldol reactions of γ-thiobutyrolactone: in all cases benzaldehyde showed a striking peculiarity compared to aliphatic aldehydes.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
Autori di Ateneo:
Link alla scheda completa:
https://air.unimi.it/handle/2434/166435

Aree Di Ricerca

Settori


Settore CHIM/06 - Chimica Organica