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Nature Inspired Crystal Engineering (NICE)

Project
NICE (Nature Inspired Crystal Engineering) aims to exploit crystal engineering strategies to deve-lop novel multi-component organic-inorganic smart materials for applications in the agriculture and food sectors.
In particular, the five groups belonging to NICE (from UniBo, UniPr, UniTo, UniMi and PoliMi) will concentrate their efforts on the design, preparation, characterization and evaluation of novel io-nic and neutral co-crystals (ICC) and metal organic frameworks (MOF) for the efficient release of nitrogen fertilizers (urea) and modulation of the activity of soil enzymes (urease and aminomo-noxygenase), and for the controlled release of antimicrobial and antifungal essential oils compo-nents (EOs) and antimicrobial agents in the environment or in the food chain.
Preferentially, NICE will use preparation methods based on solvent free mechanochemical synthe-sis, while characterization will be carried out by X-ray diffraction, NMR spectroscopy supported by calculations, by calorimetry and thermogravimetry. Product design will rely on database analysis and expert computational tools, while the biotechnological evaluation will be based on enzymatic and bacteriostatic methods.
  • Overview
  • Research Areas
  • Publications

Overview

Contributors

PROSERPIO DAVIDE MARIA   Scientific Manager  

Departments involved

Dipartimento di Chimica   Principale  

Type

PRIN2020 - PRIN bando 2020

Funder

MINISTERO DELL'ISTRUZIONE E DEL MERITO
External Organization Funding Organization

Date/time interval

April 25, 2022 - April 24, 2025

Project duration

36 months

Research Areas

Concepts


Settore CHIM/03 - Chimica Generale e Inorganica

Publications

Outputs (14)

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  • Academic Article
Photo Capture of Water by Single Crystals of a Nonporous Metal–Organic Material 
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
AMERICAN CHEMICAL SOCIETY (ACS)
2026
Academic Article
Open Access
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Collapse or capture? Guest-induced response of two structurally distinct pillared-MOFs upon exposure to pyridines and quinolines 
DALTON TRANSACTIONS
ROYAL SOCIETY OF CHEMISTRY
2025
Academic Article
Partially Open Access
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Crystalline porous frameworks based on double extension of metal–organic and covalent organic linkages 
NATURE SYNTHESIS
NATURE PUBLISHING GROUP
2025
Academic Article
Open Access
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How metal ions link in metal–organic frameworks: dots, rods, sheets, and 3D secondary building units exemplified by a Y(iii) 4,4′-oxydibenzoate 
DALTON TRANSACTIONS
ROYAL SOCIETY OF CHEMISTRY
2025
Academic Article
Open Access
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Symmetry is the Key to the Design of Reticular Frameworks 
ADVANCED MATERIALS
WILEY BLACKWELL PUBLISHING
2025
Academic Article
Open Access
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A Sodium Germanosilicide with Unusual Network Topology 
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
AMERICAN CHEMICAL SOCIETY
2024
Academic Article
Partially Open Access
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A redox active rod coordination polymer from tetrakis(4-carboxylic acid biphenyl)tetrathiafulvalene 
DALTON TRANSACTIONS
ROYAL SOCIETY OF CHEMISTRY
2024
Academic Article
Partially Open Access
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An Octacarboxylate-Linked Sodium Metal–Organic Framework with High Porosity 
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
AMERICAN CHEMICAL SOCIETY
2024
Academic Article
Partially Open Access
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Merging and Clipping Nets for the Synthesis of Three- and Two-Merged Net Metal–Organic Frameworks 
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
AMERICAN CHEMICAL SOCIETY
2024
Academic Article
Open Access
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Photocatalytic degradation of methylene blue using sunlight-powered coordination polymers constructed from a tetracarboxylate linker 
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY. A, CHEMISTRY
ELSEVIER
2024
Academic Article
Partially Open Access
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Rational Design and Reticulation of Infinite qbe Rod Secondary Building Units into Metal–Organic Frameworks through a Global Desymmetrization Approach for Inverse C3H8/C3H6 Separation 
ANGEWANDTE CHEMIE. INTERNATIONAL EDITION
WILEY BLACKWELL PUBLISHING
2024
Academic Article
Partially Open Access
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Three in one: engineering MOF channels via coordinated water arrays for regulated separation of alkanes and alkenes 
CHEMICAL SCIENCE
ROYAL SOCIETY OF CHEMISTRY
2024
Academic Article
Open Access
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Unlocking New Topologies in Zr-Based Metal–Organic Frameworks by Combining Linker Flexibility and Building Block Disorder 
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
AMERICAN CHEMICAL SOCIETY
2023
Academic Article
Open Access
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Chiral Motifs in Highly Interpenetrated Metal–Organic Frameworks Formed from Achiral Tetrahedral Ligands 
CHEMISTRY
WILEY-V C H VERLAG GMBH
2022
Academic Article
Open Access
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