Aspects of the thermogravimetric analysis of liquid mixtures as predictive or interpretation tool for batch distillation
Articolo
Data di Pubblicazione:
2021
Citazione:
Aspects of the thermogravimetric analysis of liquid mixtures as predictive or interpretation tool for batch distillation / A. Tripodi, I. Rossetti. - In: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY. - ISSN 1388-6150. - (2021). [Epub ahead of print] [10.1007/s10973-021-10990-1]
Abstract:
The thermogravimetric analysis when applied to liquid binary mixtures of acetonitrile–water and methanol–water reproduces the whole course of a batch distillation with an appreciable saving of time and materials. The experimental mass and energy balances correlate with good approximation to the vapor–liquid equilibrium compositions without the need of gas-phase measures or thermodynamic models. This technique was here applied for the first time as fast method for distillation design and complementary tool for DSC boiling-point measurements.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Acetonitrile; Distillation; DSC; Methanol; TGA; Thermogravimetry; Vapor–liquid equilibrium (VLE)
Elenco autori:
A. Tripodi, I. Rossetti
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