Controlling aggregation in highly emissive Pt(II) complexes bearing tridentate dianionic N^N^N ligands. synthesis, photophysics, and electroluminescence
Articolo
Data di Pubblicazione:
2011
Citazione:
Controlling aggregation in highly emissive Pt(II) complexes bearing tridentate dianionic N^N^N ligands. synthesis, photophysics, and electroluminescence / M. Mydlak, M. Mauro, F. Polo, M. Felicetti, J. Leonhardt, G. Diener, L. De Cola, C.A. Strassert. - In: CHEMISTRY OF MATERIALS. - ISSN 0897-4756. - 23:16(2011), pp. 3659-3667. [10.1021/cm2010902]
Abstract:
Neutral Pt(II) complexes bearing tridentate dianionic 2,6-bis(1H-1,2,4- triazol-5-yl)pyridine and ancillary alkyl-substituted pyridine ligands have been synthesized and characterized. They show bright green emission, reaching 73% photoluminescence quantum yield in deareated chloroform solution, which can be assigned to a predominantly metal-perturbed ligand-centered phosphorescence. We have followed two strategies to preserve the spectral purity of the monomeric species by varying the substituents on the chromophoric or on the ancillary ligands. However, variations in the substitution patterns only modestly affected the radiative and radiationless deactivation rate constants of the monomers. Photophysical and electrochemical properties have been measured for all the complexes and correlated with calculations using time-dependent density functional theory. The electroluminescence spectra of the brightest, nonaggregating derivative showed a better color purity than that of iridium(III) tris(phenylpyridine), thus proving that aggregation was hindered in a running electroluminescent device.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
1,2,4-triazoles; green emission; Platinum(II) complexes; tridentate ligand
Elenco autori:
M. Mydlak, M. Mauro, F. Polo, M. Felicetti, J. Leonhardt, G. Diener, L. De Cola, C.A. Strassert
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