A chemoenzymatic approach to enantiomerically pure (R)- and (S)-2,3-epoxy-2-(4-pentenyl)-propanol, a chiral building block for the synthesis of (R)- and (S)-frontalin
Articolo
Data di Pubblicazione:
1993
Citazione:
A chemoenzymatic approach to enantiomerically pure (R)- and (S)-2,3-epoxy-2-(4-pentenyl)-propanol, a chiral building block for the synthesis of (R)- and (S)-frontalin / P. Ferraboschi, S. Casati, P. Grisenti, E. Santaniello. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - 4:1(1993), pp. 9-12. [10.1016/S0957-4166(00)86004-8]
Abstract:
Enantiomerically pure (R)- and (S)-epoxyalcohols 1, chiral intermediates for the synthesis of (R)- and (S)-frontalin 2, are prepared by Pseudomonas fluorescens lipase-catalyzed transesterification in dichloromethane.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
asymmetric epoxidation; organic-synthesis; bakers-yeast; ester; (-)-frontalin; frontalin; alcohols; (S)-(-)-frontalin; resolution; alkylation
Elenco autori:
P. Ferraboschi, S. Casati, P. Grisenti, E. Santaniello
Link alla scheda completa: