Data di Pubblicazione:
2008
Citazione:
An Indium Layered MOF as Recyclable Lewis Acid Catalyst / F. Gándara, B. Gomez-Lor, E. Gutiérrez-Puebla, M. Iglesias, M. A. Monge, D.M. Proserpio, N. Snejko. - In: CHEMISTRY OF MATERIALS. - ISSN 0897-4756. - 20:1(2008), pp. 72-76.
Abstract:
By using the bent linker 4,4′-(hexafluoroisopropylidene)bis(benzoic acid) (H2hippb), whose central
atom is an sp3 carbon, a new In(III) MOF has been obtained. The structure is described as thick layers
with the bent geometry of the ligand leading to the formation of square-shaped channels, which run
inside the framework layers. This microporous, thermally stable compound has been proved to be an
efficient heterogeneous catalyst for acetalization of aldehydes. Differences in the catalytic activity when
a compound with empty or filled channels is used demonstrate that the catalytic reactions take place
inside the pores.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; HYDROGEN STORAGE; 3D FRAMEWORK; TOPOLOGY; UNITS; DESIGN
Elenco autori:
F. Gándara, B. Gomez-Lor, E. Gutiérrez-Puebla, M. Iglesias, M. A. Monge, D.M. Proserpio, N. Snejko
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