Enantioselective Mukaiyama aldol and Sakurai allylation reactions catalysed by silver(I) complexes with chiral atropisomeric chelating ligands
Articolo
Data di Pubblicazione:
2003
Citazione:
Enantioselective Mukaiyama aldol and Sakurai allylation reactions catalysed by silver(I) complexes with chiral atropisomeric chelating ligands / E. Cesarotti, S. Araneo, I. Rimoldi, S. Tassi. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - 204-205(2003), pp. 221-226.
Abstract:
Sakurai and Mukaiyama aldol reactions have been studied using (tetraMeBITIOP)silver(I) and (BITIANP)silver(I) complexes as catalysts; these complexes show high and comparable activities despite the differences in the electron availability and Lewis acid character of the phosphorus atoms.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
chiral Lewis acid; mukaiyama reaction; sakurai reaction; TetraMeBITIOP; BITIANP; chiral atropisomeric diphosphines
Elenco autori:
E. Cesarotti, S. Araneo, I. Rimoldi, S. Tassi
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