Data di Pubblicazione:
2006
Citazione:
Overcrowded organometallic platinum(II) complexes that behave as molecular gears / Raffaello Romeo, Salvatore Carnabuci, Lucia Fenech, Maria Rosaria Plutino, Alberto Albinati. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 45:27(2006), pp. 4494-4498.
Abstract:
In gear: Dynamic 1H NMR studies on some organometallic platinum(II) compounds reveal a synchronism between rotation around the Pt-P bond and the oscillation of a phenanthroline ligand between two nonequivalent exchanging sites. The system behaves as a molecular-sized analogue of a mechanical gear (see picture; C gray, N blue, O red, P purple) whose dynamic properties can be tuned through small structural changes. (Figure Presented)
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
fluxionality; molecular devices; N ligands; NMR spectroscopy; platinum
Elenco autori:
Raffaello Romeo, Salvatore Carnabuci, Lucia Fenech, Maria Rosaria Plutino, Alberto Albinati
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