Structural diversity in the products formed by the reactions of 2-arylselanyl pyridine derivatives and dihalogens
Articolo
Data di Pubblicazione:
2018
Citazione:
Structural diversity in the products formed by the reactions of 2-arylselanyl pyridine derivatives and dihalogens / R. Montis, M. Arca, M.C. Aragoni, A.J. Blake, C. Castellano, F. Demartin, F. Isaia, V. Lippolis, A. Pintus, E.J. Lenardão, G. Perin, A.E. O'Connor, S. Thurow. - In: NEW JOURNAL OF CHEMISTRY. - ISSN 1144-0546. - 42:13(2018 Jul 07), pp. 10592-10602.
Abstract:
The reactivity of the 2-arylselanyl pyridine derivatives L1-L4 towards dihalogens X2(X = I, Br) and interhalogens IX (X = Cl, Br) was studied in CHCl3or CH3CN. The solid products obtained were structurally characterized and their nature points out the preference for CT spoke adducts and for seesaw insertion adducts to be formed at the N-donor and Se-donor site, respectively. DFT calculations were performed to provide a rationale for the structural diversity observed in the products obtained.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
catalysis; chemistry (all); materials chemistry2506 metals and alloys
Elenco autori:
R. Montis, M. Arca, M.C. Aragoni, A.J. Blake, C. Castellano, F. Demartin, F. Isaia, V. Lippolis, A. Pintus, E.J. Lenardão, G. Perin, A.E. O'Connor, S. Thurow
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