SYNTHESIS OF METAL COMPLEXES WITH BIO-INSPIRED NITROGEN-CONTAINING MACROCYCLIC LIGANDS AND THEIR USE IN CATALYSIS
Tesi di Dottorato
Data di Pubblicazione:
2018
Citazione:
SYNTHESIS OF METAL COMPLEXES WITH BIO-INSPIRED NITROGEN-CONTAINING MACROCYCLIC LIGANDS AND THEIR USE IN CATALYSIS / G. Tseberlidis ; tutor: A. Caselli ; coordinator: M. Pizzotti. DIPARTIMENTO DI CHIMICA, 2018 Feb 13. 30. ciclo, Anno Accademico 2017. [10.13130/g-tseberlidis_phd2018-02-13].
Abstract:
The introduction of a pyridine moiety into the skeleton of a polyazamacrocyclic ligand affects both the thermodynamic properties and the coordination kinetics of the resulting metal complexes. These features have attracted great interest from the scientific community in recent years. The field of application of pyridine-containing macrocyclic ligands ranges from biology to supramolecular chemistry, encompassing MRI, molecular recognition, materials and catalysis. In this thesis is demonstrated the very good catalytic acivity of Ag(I), Cu(I) and Fe(III) Pyridine-containing Ligand complexes. Moreover, coordination studies have been performed leading to a complete understanding of the structural features of this class of complexes.
Tipologia IRIS:
Tesi di dottorato
Keywords:
Organometallic chemistry ; coordination chemistry ; homogeneous catalysis ; pyridine-containing ligands
Elenco autori:
G. Tseberlidis
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