Carbene X-H bond insertions catalyzed by copper(I) macrocyclic pyridine-containing ligand (PcL) complexes
Articolo
Data di Pubblicazione:
2017
Citazione:
Carbene X-H bond insertions catalyzed by copper(I) macrocyclic pyridine-containing ligand (PcL) complexes / G. Tseberlidis, A. Caselli, R. Vicente. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 835(2017 May 01), pp. 1-5.
Abstract:
A catalytic system comprising copper(I) and macrocyclic pyridine-containing ligands (Pc-L) proves capable of promoting carbene Si-H bond insertions using diazo compounds as the carbene source. This catalytic system showed broad scope and a remarkable robustness as indicated by high TON numbers (up to 30000). Moreover, the use of enynones as carbene sources proved also feasible in hydrosilane insertion using this catalytic system. Finally, the insertion in O-H and N-H bonds of phenols and anilines, respectively, has been also demonstrated.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Si-H bond insertions; Diazoalkanes; Macrocyclic ligands; Copper complexes; Pyridine-containing ligands
Elenco autori:
G. Tseberlidis, A. Caselli, R. Vicente
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