Contrasted photochromic and luminescent properties in dinuclear Pt(II) complexes linked through a central dithienylethene unit
Articolo
Data di Pubblicazione:
2016
Citazione:
Contrasted photochromic and luminescent properties in dinuclear Pt(II) complexes linked through a central dithienylethene unit / J. Boixel, Y. Zhu, H. Le Bozec, M.A. Benmensour, A. Boucekkine, K.M. Wong, A. Colombo, D. Roberto, V. Guerchais, D. Jacquemin. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 52:63(2016), pp. 9833-9836. [10.1039/c6cc03431d]
Abstract:
We disclose two unprecedented complexes built with a central dithienylethene photochrome connecting two cyclometalated Pt(ii) moieties either on the reactive carbon atoms or on the lateral non-reactive carbon atoms of the photochrome. The two systems show vastly different properties that are rationalised thanks to quantum-chemical calculations.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Cyclometalated platinim(II) complexes; nonlinear-optical properties; PI-PI interactions; metal-complexes; switches; state; organometallics; molecules; driven; bridge
Elenco autori:
J. Boixel, Y. Zhu, H. Le Bozec, M.A. Benmensour, A. Boucekkine, K.M. Wong, A. Colombo, D. Roberto, V. Guerchais, D. Jacquemin
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