Novel Fullerene Platinum Alkynyl Complexes with High Second-Order Nonlinear Optical Properties as a Springboard for NLO-Active Polymer Films
Articolo
Data di Pubblicazione:
2016
Citazione:
Novel Fullerene Platinum Alkynyl Complexes with High Second-Order Nonlinear Optical Properties as a Springboard for NLO-Active Polymer Films / C. Dragonetti, A. Colombo, M. Fontani, D. Marinotto, F. Nisic, S. Righetto, D. Roberto, F. Tintori, S. Fantacci. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 35:7(2016), pp. 1015-1021. [10.1021/acs.organomet.6b00094]
Abstract:
The synthesis and second-order nonlinear optical (NLO) properties of seven novel fullerene-C60 derivatives are reported. In these donor-bridge-acceptor systems, the fullerene unit (acceptor) is connected through a cyclopropane ring to an ethynyl thienyl fragment (bridge) which binds a trimethylsilyl or platinum alkynyl fragment (donor). All derivatives are NLO-active, as determined by the electric field induced second harmonic generation technique, but the fullerene platinum alkynyl complexes are characterized by a particularly large second-order NLO response. Substitution of the thienyl fragment by a terthiophene leads to an increase of the NLO performance by using trimethylsilyl as a donor group, whereas no effect is observed in the case of platinum derivatives. Remarkably, fullerene platinum alkynyl complexes can be dispersed in poly(methyl methacrylate) or polystyrene, affording NLO-active polymer films.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Organic Chemistry; Physical and Theoretical Chemistry; Inorganic Chemistry
Elenco autori:
C. Dragonetti, A. Colombo, M. Fontani, D. Marinotto, F. Nisic, S. Righetto, D. Roberto, F. Tintori, S. Fantacci
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