Ruthenium-Catalyzed C-H Bond Functionalizations of 1,2,3-Triazol-4-yl-Substituted Arenes: Dehydrogenative Couplings Versus Direct Arylations
Articolo
Data di Pubblicazione:
2010
Citazione:
Ruthenium-Catalyzed C-H Bond Functionalizations of 1,2,3-Triazol-4-yl-Substituted Arenes: Dehydrogenative Couplings Versus Direct Arylations / L. Ackermann, P. Novák, R. Vicente, V. Pirovano, H.K. Potukuchi. - In: SYNTHESIS. - ISSN 0039-7881. - 2010:13(2010 Apr 18), pp. C02010SS.2245-C02010SS.2253. [10.1055/s-0029-1220010]
Abstract:
The chemoselectivity of ruthenium-catalyzed C-H bond arylations on triazol-4-yl-substituted arenes was found to depend on the substitution pattern of both substrates. While various aryl chlorides led to products stemming from direct arylations, ortho-substituted aryl halides in combination with ortho-alkylated arenes preferentially resulted in oxidative homo-couplings.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
L. Ackermann, P. Novák, R. Vicente, V. Pirovano, H.K. Potukuchi
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