Pd-modified Au on carbon as an effective and durable catalyst for the direct oxidation of HMF to 2,5-furandicarboxylic acid
Articolo
Data di Pubblicazione:
2013
Citazione:
Pd-modified Au on carbon as an effective and durable catalyst for the direct oxidation of HMF to 2,5-furandicarboxylic acid / A. Villa, M. Schiavoni, S. Campisi, G.M. Veith, L. Prati. - In: CHEMSUSCHEM. - ISSN 1864-5631. - 6:4(2013 Apr), pp. 609-612. [10.1002/cssc.201200778]
Abstract:
Mixed noblility: We show that the modification of a gold/carbon catalyst with platinum or palladium produces stable and recyclable catalysts for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA): the support and nanoparticle chemistry directly mediate the selective oxidation of terminal hydroxyl groups in bio-derived HMF. This finding is a significant advance over current conversion technology because of the technological importance of FDCA.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
alloys; gold; hydroxymethylfurfural; oxidation; palladium
Elenco autori:
A. Villa, M. Schiavoni, S. Campisi, G.M. Veith, L. Prati
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