Construction of N,N′-di(3-pyridyl)adipoamide-based Zn(ii) and Cd(ii) coordination networks by tuning the isomeric effect of polycarboxylate ligands
Articolo
Data di Pubblicazione:
2013
Citazione:
Construction of N,N′-di(3-pyridyl)adipoamide-based Zn(ii) and Cd(ii) coordination networks by tuning the isomeric effect of polycarboxylate ligands / P.-C. Cheng, M.-H. Wu, M.-Y. Xie, W.-J. Huang, H.-Y. He, T.-T. Wu, Y.-C. Lo, D.M. Proserpio, J.-D. Chen. - In: CRYSTENGCOMM. - ISSN 1466-8033. - 15:47(2013), pp. 10346-10357.
Abstract:
Eight new Zn(II) and Cd(II) coordination networks containing N,N′-di(3-pyridyl)adipoamide (L) and polycarboxylate
ligands, {[Zn2(2,5-PDC)2(L)(H2O)2]·2H2O}∞ (H2PDC = 2,5-pyridinedicarboxylic acid), 1, [Zn2(2,6-PDC)2(L)]∞,
2, {[Zn2(3,4-PDC)2(L)(H2O)6]·4H2O}∞, 3, {[Cd(2,6-PDC)(L)(H2O)]·4H2O}∞, 4, [Zn(1,3,5-HBTC)()]∞ (H3BTC =
benzenetricarboxylic acid), 5, {[Cd(1,2,3-HBTC)(L)(H2O)]·H2O}∞, 6, {[Cd2(1,3,5-HBTC)2(L)(H2O)2]·2H2O}∞, 7, and {[Zn3(1,2,4-BTC)2(L)(H2O)4]·4H2O}∞, 8, have been synthesized by hydrothermal reactions and characterized by single crystal X-ray crystallography. Structural analysis reveals that 1 and 2 form pleated hcb layers with 1D helical chains, in which the layers of 1 interdigitate with each other and those of 2 are linked by the π–π stacking interactions.
Complexes 3 and 4 exhibit 1D ladders with single and double rungs, respectively, whereas 5 shows a 2D
pleated net with the sql topology, 6 displays a 3D dia coordination network and 7 forms a 2D structure with the
(6^3)(6^6)-3,4L88 topology. The BTC3− ligands in 8 adopt the μ4-bonding modes, resulting in a 3D coordination
network with the rare (6^5·8)-hxg-d-4-P2/c topology. The various bonding modes, the ligand-isomerism of the
polycarboxylate ligands and the identity of the metal center play important roles in determining the structural diversity. Their thermal and luminescent properties are also discussed.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
P.-C. Cheng, M.-H. Wu, M.-Y. Xie, W.-J. Huang, H.-Y. He, T.-T. Wu, Y.-C. Lo, D.M. Proserpio, J.-D. Chen
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