Data di Pubblicazione:
2012
Citazione:
Predictive modeling of the vibrational quenching in emitting lanthanides complexes / A. Monguzzi, A. Milani, A. Mech, L. Brambilla, R. Tubino, C. Castellano, F. Demartin, F. Meinardi, C. Castiglioni. - In: SYNTHETIC METALS. - ISSN 0379-6779. - 161:23-24(2012), pp. 2693-2699. [10.1016/j.synthmet.2011.10.002]
Abstract:
Organic complexes of lanthanides trivalent ions such as Nd3+ and Er3+ are receiving increasing attention
in view of their use as dopants in polymeric telecommunication devices. Their employment is however
currently limited by their small emission quantum yield (QY) due to non-radiative deactivation of near
infrared (NIR) transitions through electronic-vibrational energy transfer (ET). A complete modeling of
this quenching effect is presented here and successfully tested on a purpose-made Er3+ complex. This
method provides “a priori” information/predictions regarding the emission properties of new complexes
thus establishing useful guidelines for the design and synthesis of new molecules and for the engineering
of materials suitable in technological applications.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Near infrared emitters ; Lanthanides complexes ; Emission quenching ; Vibrational intensities
Elenco autori:
A. Monguzzi, A. Milani, A. Mech, L. Brambilla, R. Tubino, C. Castellano, F. Demartin, F. Meinardi, C. Castiglioni
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