ZEROVALENT PLATINUM CHEMISTRY .12. UNEXPECTED REACTIVITY OF [PT(PPH3)2(O2)] TOWARDS ORTHO AND PARA QUINONES AND THE STRUCTURES OF 1 1 ADDUCTS WITH P-BENZOQUINONE AND 1,4-NAPHTHOQUINONE
Articolo
Data di Pubblicazione:
1991
Citazione:
ZEROVALENT PLATINUM CHEMISTRY .12. UNEXPECTED REACTIVITY OF [PT(PPH3)2(O2)] TOWARDS ORTHO AND PARA QUINONES AND THE STRUCTURES OF 1 1 ADDUCTS WITH P-BENZOQUINONE AND 1,4-NAPHTHOQUINONE / M. PIZZOTTI, S. CENINI, R. UGO, F. DEMARTIN. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - :1(1991), pp. 65-70.
Abstract:
The reaction of [Pt(PPh3)2(O2)] with both o- and p-benzoquinones produces only 1:1 adducts characterised by a pseudo-ozonide metallacycle involving one carbonyl group with a spiranic steric arrangement. Strangely the second carbonyl group of the quinone does not react with an excess of [Pt(PPh3)2(O2)]. The X-ray structures of the adducts with p-benzoquinone and 1,4-naphthoquinone show a skew conformation of the metallacycle with the quinone moiety still planar. Reaction with [Pt(PPh3)2(O2)] produces only a slight perturbation of the π-electronic conjugated structure of the quinone, since the C=O bond length of the free carbonyl group does not change. Molecular models suggest the absence of steric hindrance for a second pseudo-ozonide metallacycle involving the para carbonyl group. It is suggested that the lack of reactivity could be of kinetic origin.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
M. PIZZOTTI, S. CENINI, R. UGO, F. DEMARTIN
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