Phosphorus longitudinal relaxation times as a probe of the coordination site of the phosphine ligands in rhenium complexes
Articolo
Data di Pubblicazione:
1996
Citazione:
Phosphorus longitudinal relaxation times as a probe of the coordination
site of the phosphine ligands in rhenium complexes / T. Beringhelli, G. D'Alfonso, M. Freni, A. Minoja. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - 35:8(1996), pp. 2393-2393-\&.
Abstract:
P-31 relaxation in P-donor ligands bound to rhenium depends, at low
fields, on (1)J(Re-P), and therefore is sensitive to the stereochemistry
of the other ligands. The comparison of T-1's can be used as a probe of
the coordination geometry of the P-ligands in the case of isomers or
when the ligands are bound differently to the same metal or (in
polynuclear compounds) bound to different metals, provided that these
have the same coordination sphere.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
T. Beringhelli, G. D'Alfonso, M. Freni, A. Minoja
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