Spectroscopic titration of {[Re-4(mu(3)-H)(4)(CO)(12)] with chloride ions. An electron-precise tetranuclear cluster as intermediate in the transformation of a tetranuclear unsaturated cluster into trinuclear unsaturated anions}
Articolo
Data di Pubblicazione:
1996
Citazione:
Spectroscopic titration of {[Re-4(mu(3)-H)(4)(CO)(12)] with chloride
ions. An electron-precise tetranuclear cluster as intermediate in the
transformation of a tetranuclear unsaturated cluster into trinuclear
unsaturated anions} / T. Beringhelli, G. D'Alfonso, M. Garavaglia. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - :8(1996), pp. 1771-1773.
Abstract:
The unsaturated tetrahedral cluster {[Re-4(mu(3)-H)(4)(CO)(12)] easily
added halide ions giving [Re(4)H(4)X(CO)(12)](-) anions, which in the
presence of even poor donor species underwent fragmentation to
unsaturated triangular cluster anions.}
added halide ions giving [Re(4)H(4)X(CO)(12)](-) anions, which in the
presence of even poor donor species underwent fragmentation to
unsaturated triangular cluster anions.}
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
T. Beringhelli, G. D'Alfonso, M. Garavaglia
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