TETRABUTYLAMMONIUM FLUORIDE - A POWERFUL CATALYST FOR THE REGIOSELECTIVE OPENING OF EPOXIDES WITH THIOLS
Articolo
Data di Pubblicazione:
1994
Citazione:
TETRABUTYLAMMONIUM FLUORIDE - A POWERFUL CATALYST FOR THE REGIOSELECTIVE OPENING OF EPOXIDES WITH THIOLS / D. ALBANESE, D. LANDINI, M. PENSO. - In: SYNTHESIS. - ISSN 0039-7881. - :1(1994), pp. 34-36.
Abstract:
Tetrabutylammonium fluoride (1) catalyses under mild conditions the opening of epoxides 2a-k with thiols 3-6 to produce the corresponding beta-hydroxy thioethers 7-11 in excellent yields (88-100%) and with high regioselectivity. Furthermore, O-protected glycidols react without any loss of the protective group.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
D. ALBANESE, D. LANDINI, M. PENSO
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