Reaction between the diaqua form of cisplatin and 2-methylsulfanylphenylphosphonic acid yields a dinuclear phosphonato-bridged complex via NH3 elimination
Articolo
Data di Pubblicazione:
2000
Citazione:
Reaction between the diaqua form of cisplatin and 2-methylsulfanylphenylphosphonic acid yields a dinuclear phosphonato-bridged complex via NH3 elimination / C. Mauger, M. Vazeux, A. Albinati, J. Kozelka. - In: INORGANIC CHEMISTRY COMMUNICATIONS. - ISSN 1387-7003. - 3:12(2000 Dec), pp. 704-707.
Abstract:
Reaction between cis-[Pt(NH3)(2)(H2O)(2)](2+) and (2-methylsulfanyl)phenyl phosphonic acid (H(2)mspp) did not yield the expected cis-diammine [(2-methylsulfanylphenyl)phosphonato]platinum(II) but the dimeric compound [(Pt(mspp)(NH3)}(2)] . 6H(2)O in which the dianionic mspp(2-) ligand acts both as chelator and bridging ligand. Thus, the high trans-effect of the sulfanyl group apparently leads to elimination of one NH3 ligand. An X-ray crystal structure analysis of the dimeric complex is reported.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
platinum complexes; 2-methylsulfanylphenyl phosphonic acid; X-ray diffractometry
Elenco autori:
C. Mauger, M. Vazeux, A. Albinati, J. Kozelka
Link alla scheda completa: