Data di Pubblicazione:
1997
Citazione:
Facile conversion of sulfilimines into sulfoximines using dioxiranes / N. Gaggero, L. D'Accolti, S. Colonna, R. Curci. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 38:31(1997), pp. 5559-5562.
Abstract:
Employing dimethyldioxirane, the direct conversion of several N-(p-tolylsulfonyl)sulfilimines and of one N-(acetyl)sulfilimine into the corresponding sulfoximines was achieved in high yield under mild conditions. Optically active S-(p-tolyl)-S-methyl-N-(p-tolylsulfonyl)sulfilimine could be transformed into its sulfoximine in high enantiomeric excess with retention of configuration. The effect of substituents indicates that the oxidation involves electrophilic O-transfer from the dioxirane to the sulfilimine sulfur.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Dioxiranes; Oxidation; Sulfilimines; Sulfoximines
Elenco autori:
N. Gaggero, L. D'Accolti, S. Colonna, R. Curci
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