[Fe(en)(3)](2)(Hg2Te9): A novel tellurometalate containing one-dimensional chains of weakly bound zintl anions (Hg2Te9)(4-)
Articolo
Data di Pubblicazione:
1995
Citazione:
[Fe(en)(3)](2)(Hg2Te9): A novel tellurometalate containing one-dimensional chains of weakly bound zintl anions (Hg2Te9)(4-) / J. Li, B. Rafferty, S. Mulley, D.M. Proserpio. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - 34:26(1995), pp. 6417-6418.
Abstract:
[Fe(en)3]2Hg2Te9, a novel tellurometalate containing a new type of Zintl ion (Hg2Te9)4-, has been synthesized from solvothermal reactions. Single-crystal X-ray diffraction analysis shows that this compounds contains one-dimensional chains of weakly bound (Hg2Te9)4- ions separated by iron tris(ethylenediamine). Not only is [Fe(en)3]2Hg2Te9 the first tellurometalate produced from solvothermal reactions, it is also the first example of an interesting structure containing a Zintl ion and transition metal complex (as counterion) in the same phase.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
J. Li, B. Rafferty, S. Mulley, D.M. Proserpio
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