Data di Pubblicazione:
1981
Citazione:
The catalytic transformation of nitrosobenzene into azoxy and azobenzene / F. Porta, M. Pizzotti, S. Cenini. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 222:2(1981), pp. 279-284. [10.1016/S0022-328X(00)89156-1]
Abstract:
Nitrosobenzene is converted into azoxybenzene in alcoholic media in the presence of Ru(CO)3(PPh3)2 as catalyst and under an inert atmosphere; Fe(CO)3(PPh3)2 and palladium complexes such as PdL2Cl2 (L PhNO, p-MeC6H4NH2, PPh3) and Pd3(CO)3(PPh3)4, are less active as catalysts. Under CO pressure and with Ru(CO)3(PPh3)2 as catalyst, nitrosobenzene is converted into azobenzene and aniline, while azoxybenzene gives azobenzene.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
F. Porta, M. Pizzotti, S. Cenini
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