Crystallographic and nuclear magnetic resonance studies of carbonyl(η3-methylallyl)(trichlorostannyl) complexes of platinum(II) and palladium(II)
Articolo
Data di Pubblicazione:
1989
Citazione:
Crystallographic and nuclear magnetic resonance studies of carbonyl(η3-methylallyl)(trichlorostannyl) complexes of platinum(II) and palladium(II) / M. Grassi, S. V. Meille, A. Musco, R. Pontellini, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - :4(1989), pp. 615-621.
Abstract:
The complexes [M(η3-C4H7)(SnCl3)(CO)] [C4H7 = 2-methylallyl, M = Pt(1) or Pd(2)] have been prepared and characterized. Their solution behaviour has been studied by n.m.r. spectroscopy, the compounds being dynamic through dissociation of the CO ligand. The X-ray structures of (1) and (2) are reported. Complex (2) is the first mononuclear palladium carbonyl to be characterized by X-ray diffraction. The different stabilities of the two isostructural complexes are correlated with the subtle differences in bonding observed in the crystal structures.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
M. Grassi, S. V. Meille, A. Musco, R. Pontellini, A. Sironi
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