Isolation of the mixed-metal carbonyl cluster anion [RuIr3(CO)9(μ-CO)3]-. Crystal structure of its bis(triphenylphosphine)iminium salt
Articolo
Data di Pubblicazione:
1985
Citazione:
Isolation of the mixed-metal carbonyl cluster anion [RuIr3(CO)9(μ-CO)3]-. Crystal structure of its bis(triphenylphosphine)iminium salt / A. Fumagalli, F. Demartin, A. Sironi. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 279:3(1985), pp. c33-c33-c36.
Abstract:
The anion [RuIr3(CO)12]- has been isolated as one of the products from decomposition of [RuIr4(CO)15]2- in the absence of CO, and the structure of the bis(triphenylphosphine)iminium salt has been determined by X-ray diffraction. The anion is isoelectronic and isostructural with CO4(CO)12 and Rh4(CO)12, with the Ru atom located at one vertex of the metal triangle, which bears three edge-bridging carbonyls. © 1985.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
A. Fumagalli, F. Demartin, A. Sironi
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