Data di Pubblicazione:
2005
Citazione:
1,3-Dipolar cycloadditions of MeOPEG-bounded azides / G. Molteni, P. Del Buttero. - In: TETRAHEDRON. - ISSN 0040-4020. - 61:21(2005), pp. 4983-4987. [10.1016/j.tet.2005.03.049]
Abstract:
1,3-Dipolar cycloadditions of MeOPEG-supported azide 2 with a variety of dipolarophiles have been studied. 1-MeOPEGsupported
1,2,3-triazoles 4 and 5, 1,2,3,4-tetrazoles 12 and aziridine 14 were obtained in nearly quantitative yields. The removal of the
MeOPEG moiety from the 1,2,3-triazole nucleus was achieved by acidic cleavage of the cycloadduct mixtures 4 and 5 giving 4- and 5-substituted-1,2,3-triazoles 6 and 7.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Azides ; 1,3-Dipolar cycloadditions ;
Azoles ; Polymer-supported synthesis
Elenco autori:
G. Molteni, P. Del Buttero
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