Recent advances in the electromotive force method for determining transference numbers of electrolytes and characterizing new salt bridges
Articolo
Data di Pubblicazione:
1998
Citazione:
Recent advances in the electromotive force method for determining transference numbers of electrolytes and characterizing new salt bridges / P.R. Mussini, T. Mussini. - In: JOURNAL OF APPLIED ELECTROCHEMISTRY. - ISSN 0021-891X. - 28:12(1998 Dec), pp. 1305-1311.
Abstract:
Recent transference-cell e.m.f. data sets for various 1:1 electrolytes in aqueous-organic solvent mixtures obtained in these laboratories for the determination of ionic transference numbers have been aggregated with earlier sets for 1:1 electrolytes in aqueous solutions and reexamined in the light of a new theoretical approach accounting for the solvent transfer phenomena accompanying ionic transfer. The potentialities and the precision of the transference-cell e.m.f. method have been highlighted, and new salt bridges, for use in aqueous-organic solvents, have been thereby characterized.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Concentration cells; Salt bridges; Transference numbers
Elenco autori:
P.R. Mussini, T. Mussini
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