Data di Pubblicazione:
1999
Citazione:
Synthesis of polymer-bound Fischer chromium alkoxy and aminocarbene complexes / S. Maiorana, P. Seneci, T. Rossi, C. Baldoli, M. Ciraco, E. De Magistris, E. Licandro, A. Papagni, S. Provera. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 40:18(1999), pp. 3635-3638.
Abstract:
A series of polymer-bound Fischer chromium alkoxy and amino carbene type I complexes were synthesized by the thermal exchange of a CO ligand in chromium pentacarbonyl carbenes 2 with triphenyl phosphine resin 1. The supported alkoxycarbene 3a proved to be reactive towards primary amines, and afforded the polymer-bound aminocarbenes 5. Type II aminocarbenes were also prepared by reacting polymer-supported aminoacids with alkoxycarbene 2a.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Phosphino chromium carbonyls; Polymer-bound Fischer carbenes; Solid phase synthesis
Elenco autori:
S. Maiorana, P. Seneci, T. Rossi, C. Baldoli, M. Ciraco, E. De Magistris, E. Licandro, A. Papagni, S. Provera
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