Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands
Articolo
Data di Pubblicazione:
2012
Citazione:
Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands / J.-J. Cheng, Y.-T. Chang, C.-J. Wu, Y.-F. Hsu, C.-H. Lin, D.M. Proserpio, J.-D. Chen. - In: CRYSTENGCOMM. - ISSN 1466-8033. - 14:2(2012), pp. 537-543. [10.1039/c1ce06019h]
Abstract:
The syntheses, structures and thermal properties of three coordination networks [Zn(L1)(1,4-BDC)].H2O (L1 = N,N'-di(4-pyridyl)adipoamide; 1,4-H2BDC = 1,4-benzenedicarboxylic acid), 1, [Cd(L1)(1,4-BDC)].2H2O, 2, and [Zn2(L2)(1,4-BDC)2].2CH3OH (L2 = N,N'-di(4-pyridyl)dodecanamide), 3, are
reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn2(COO)2 dimer
decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.
Tipologia IRIS:
01 - Articolo su periodico
Elenco autori:
J.J. Cheng, Y.T. Chang, C.J. Wu, Y.F. Hsu, C.H. Lin, D.M. Proserpio, J.D. Chen
Link alla scheda completa:
Link al Full Text: