Enhancing Cotton Fabrics Through Grafting of Glycine-Based Polyamidoamine

Durable polyamidoamine (PAA) coatings were covalently grafted onto cotton by
applying a water-soluble, glycine-based PAA (M-GLY) through a radical polymerization
mechanism. M-GLY oligomers of different chain lengths, terminated with bisacrylamide
groups, were synthesized via polyaddition of N,N′-methylenebisacrylamide and glycine at
molar ratios of 1:0.9, 1:0.85, and 1:0.8. Cotton strips were then impregnated with differently
concentrated (10 and 20 wt.%) aqueous solutions of the M-GLY oligomers in the presence
of potassium persulfate, which oxidized cellulose and generated radicals that initiated
polymerization of the M-GLY terminals, thereby enabling covalent grafting onto cotton.
This process yielded M-GLY-grafted cotton (COT-g-M-GLY) with 2–15% add-on levels.
Scanning electron microscopy revealed uniform surface coverage and penetration of the coating into fiber interiors. Grafting did not alter cellulose crystallinity—65% vs. 64% for grafted and virgin cotton. However, thermogravimetric analysis showed that COT-g-MGLY exhibited lower thermo-oxidative stability than M-GLY-adsorbed cotton (COT/MGLY) at similar add-ons. Flame-retardancy tests indicated that COT-g-M-GLY reduced the burning rate (by 10% to 30%) but did not achieve self-extinguishing behavior, unlike COT/M-GLY. Despite this, COT-g-M-GLY provided good protection against UV-induced photodegradation. After accelerated UVA–UVB exposure, cotton samples with 10% M-GLY add-on showed a significantly reduced yellowing rate compared to untreated cotton, as confirmed by spectrophotometric analysis.