Dispersion-Driven Hydrogen Bonding : Predicted Hydrogen Bond between Water and Platinum(II) Identified by Neutron Diffraction
Articolo
Data di Pubblicazione:
2010
Citazione:
Dispersion-Driven Hydrogen Bonding : Predicted Hydrogen Bond between Water and Platinum(II) Identified by Neutron Diffraction / S. Rizzato, J. Bergès, S. A. Mason, A. Albinati, J. Kozelka. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 49:41(2010), pp. 7440-7443. [10.1002/anie.201001892]
Abstract:
An alternative to classical? In square-planar d8 complexes the metal ion can interact with axial H2O molecules either as a Lewis acid or as a Lewis base. Ab initio calculations predicted that uncharged PtII complexes form a hydrogen-bond-like interaction with H2O, in which PtII acts as a Lewis base. Such a nonclassical O-H Pt hydrogen bond has now been identified in crystals of trans-[PtCl2 (NH3)(N-glycine)] H2O by neutron diffraction.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Ab initio calculations; Hydrogen bonds; Neutron diffraction; Platinum; X-ray diffraction
Elenco autori:
S. Rizzato, J. Bergès, S.A. Mason, A. Albinati, J. Kozelka
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