Au-Pd/AC as catalysts for alcohol oxidation : effecf of reaction parameters on catalytic activity and selectivity
Articolo
Data di Pubblicazione:
2009
Citazione:
Au-Pd/AC as catalysts for alcohol oxidation : effecf of reaction parameters on catalytic activity and selectivity / A. Villa, N. Janijc, P. Spontoni, D. Wang, D. S. Su, L. Prati. - In: APPLIED CATALYSIS A: GENERAL. - ISSN 0926-860X. - 364:1-2(2009), pp. 221-228. [10.1016/j.apcata.2009.05.059]
Abstract:
The oxidation of different alcohols with molecular oxygen in water has been investigated using a range of activated carbon-supported Au–Pd bimetallic catalysts. The effect of the Au–Pd ratio on the conversion and selectivity was observed and a synergistic effect is present in a large range of the Au–Pd ratio, being maximized for Au80–Pd20 composition instead of Au90–Pd10 shown in glycerol oxidation [A. Villa, C. Campione, L. Prati, Catal. Lett. 115 (2007) 133]. Moreover the enhancement of conversion observed by adding a base resulted greater for gold-rich catalysts rather than for palladium-rich ones.
The effect of the alcohol concentration and the metal/substrate ratio in the presence or the absence of the base was also studied revealing substantial differences in terms of both activity and selectivity. At 1 M concentration under biphasic conditions benzyl alcohol has been selectively oxidized to benzaldehyde (S90 = 98%) even in the presence of NaOH with a TOF of 18,000 h−1 using Au60–Pd40/AC as the catalyst
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
Alcohol oxidation; Gold-palladium alloy
Elenco autori:
A. Villa, N. Janijc, P. Spontoni, D. Wang, D.S. Su, L. Prati
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