Charge-transfer adducts of N-methylthiazolidine-2-thione with IBr and I2 : an example of polymorphism featuring interpenetrationg three-dimensional subcomponent assemblies and halogen-pi-halogen weak interactions
Articolo
Data di Pubblicazione:
2007
Citazione:
Charge-transfer adducts of N-methylthiazolidine-2-thione with IBr and I2 : an example of polymorphism featuring interpenetrationg three-dimensional subcomponent assemblies and halogen-pi-halogen weak interactions / M. C. Aragoni, M. Arca, F. Demartin, F. A. Devillanova, T. Gelbrich, A. Garau, M.B. Hursthouse, F. Isaia, V. Lippolis. - In: CRYSTAL GROWTH & DESIGN. - ISSN 1528-7483. - 7:7(2007), pp. 1284-1290. [10.1021/cg0606545]
Abstract:
Two polymorphic forms of the 1:1 charge-transfer adduct between N-methylthiazolidine-2-thione and IBr have been isolated: their structural analyses by a recently reported procedure for comparison of multiple crystal forms of the same molecular structure reveal some interesting geometrical 3D similarity relationships that ca be interpreted in terms of different sets of halogen...pi...halogen weak interactions. The 1:1 charge transfer adduct with I2 has also been isolated and structurally characterized on proven to be isostructural with one of the two polymorphic forms of the IBr adduct.
Tipologia IRIS:
01 - Articolo su periodico
Keywords:
charge-transfer adducts ; polymorphic forms.
Elenco autori:
M.C. Aragoni, M. Arca, F. Demartin, F.A. Devillanova, T. Gelbrich, A. Garau, M.B. Hursthouse, F. Isaia, V. Lippolis
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